Highly Effi cient Chain End Derivatization of Selenol-Ended Polystyrenes by Nucleophilic Substitution Reactions

Weihong Lu , Xiaowei An , Feng Gao , Jian Zhu , Nianchen Zhou , Zhengbiao Zhang , * Xiangqiang Pan , * Xiulin Zhu *

本论文通过端基硒醇与卤代烃、丙烯酸酯、五氟苯乙烯等经亲核取代反应或Michael加成反应对聚苯乙烯进行端基修饰，反应条件温和，有效实现了聚合物的末端改性。