张正彪

  • 姓名: 张正彪
  • 职称:教授(博士生导师)
  • 联系电话: 0512-65880819 传真:0512-65882787
  • E-mail: zhangzhengbiao@suda.edu.cn
教育经历
 
博士(20039~200712月)苏州大学,高分子化学与物理
 
硕士(19979~20006月)苏州大学,高分子化学与物理
 
本科(19939~19976月)苏州大学,化学工程
 
 

工作经历

2000年8月~现在   苏州大学,材料与化学化工学部

2007年8月~2008年8月,新加坡国立大学,博士后

2012年2月~2013年2月,美国阿克伦大学,访问学者

2015年6月~2015年8月,日本名古屋大学,访问教授

 

 

研究兴趣

1.可控聚合机理及新方法开发

2.序列可控聚合物的合成;

3.拓扑结构聚合物的设计与合成

4.功能大分子的精密设计与合成

 

 

荣誉

教育部自然科学二等奖,排五,2010;

江苏省自然科学进步二等奖,排五,2010;

苏州大学优秀博士论文,2008;

苏州大学苏鑫科研奖,2008;

指导国家级大学生创新性实验计划(2010)和校级大学生创新性计划(2009)各1项,

结题均为优秀。

主讲《化工原理》课程获苏州大学精品课程。

 

 

近年来主持的部分项目

 

1)国家自然科学基金面上项目:基于可逆Diels-Alder反应构建复杂拓扑链结构以及分子量/序列

明确的聚合物(21674072),68万元。2017.1-2020.12,主持。

2)国家自然科学基金面上项目:基于非共价键相互作用和可控自由基聚合的大分子精密合成

(21374068),83万元。2014.1-2017.12,主持。

3)国家自然科学基金面上项目:室温下零价铁调控的“活性”/可控自由基聚合

21174094),62万元。2012.1-2015.12,主持。

4)国家自然科学基金青年基金项目:单电子转移“活性”自由基聚合(SET-LRP)的机理研究

(20904036),19万元,2010.1-2012.12,主持。

5)江苏省高校自然科学研究重大项目:基于“活性”自由基聚合和分子间弱相互作用的大分子精

密合成(12KJA150007),20万元,2012.8-2015.12,主持

 
 
网站
 
 
近年论文代表作
 

1.   Yuxuan Ji, Liuqiao Zhang, Xue Gu, Wei Zhang, Nianchen Zhou, Zhengbiao Zhang,* and Xiulin Zhu. Sequence-Controlled Polymers with Furan-Protected Maleimide as a Latent Monomer. Angew. Chem. Int. Ed. 2017, DOI: 10.1002/anie.201610305.

2.   Zhihao Huang,  Yanyan Zhou,  Zimu Wang,  Ying Li,  Wei Zhang,  Nianchen Zhou,  Zhengbiao Zhang*  and  Xiulin Zhu*. Recent Advances of CuAAC Click Reaction In Building Cyclic Polymer. Chinese Journal of Polymer Science 2017, 35, 317-341. Review article.

3.   Zhaoxiong Cai, Weihong Lu, Feng Gao, Xiangqiang Pan, * Jian Zhu, Zhengbiao Zhang* Xiulin Zhu*. Diselenide-Labeled Cyclic Polystyrene with Multiple Responses: Facile Synthesis, Tunable Size, and Topology. Macromol. Rapid Commun. 2016, 37, 865-871.

4.   Wei Chen, Yanyan Zhou, Ying Li, Jun Sun, Xiangqiang Pan, Qian Yu, Nianchen Zhou, Zhengbiao Zhang* and Xiulin Zhu. Shape-memory and self-healing polyurethanes based on cyclic poly(ε-caprolactone). Polym. Chem., 2016, 7, 6789-6797.

5.   Junfei Zhao, Yanyan Zhou, Yu Zhou, Nianchen Zhou, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu. A straightforward approach for the one-pot synthesis of cyclic polymers from RAFT polymers via thiol–Michael addition. Polym. Chem., 2016, 7, 1782-1791.

6.   Shuangshuang Zhang, Lu Yin, Wei Zhang*, Zhengbiao Zhang* and Xiulin Zhu*. Synthesis of Diverse Cyclic-Brush Polymers with Cyclic Polystyrene as Universal Template via Grafting-from Approach. Polym. Chem., 2016, 7, 2112-2120.

7.   Qingqing Liu, Huaqiao Wu, Liuqiao Zhang, Yu Zhou, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu. RAFT polymerization of N-vinylpyrrolidone mediated by cyanoprop-2-yl-1-dithionaphthalate in the presence of a fluoroalcohol: the possibility of altering monomer properties by hydrogen bonding? Polym. Chem., 2016, 7, 2015-2021.

8.   Chunlai Ding, Caiwei Fan, Ganquan Jiang, Xiangqiang Pan, Zhengbiao Zhang*, Jian Zhu* and Xiulin Zhu. Photocatalyst-Free and Blue Light-Induced RAFT Polymerization of Vinyl Acetate at Ambient Temperature. Macromolecular Rapid Communications. 2015, 36, 2181-2185.

9.   Yunshu Wang, Shuangshuang Zhang, Laibing Wang, Wei Zhang*, Nianchen Zhou, Zhengbiao Zhang* and Xiulin Zhu*. The Suzuki coupling reaction as a post-polymerization modification: a promising protocol for construction of cyclic-brush and more complex polymers. Polym. Chem., 2015, 6, 4669-4677.

10.   Feng Gao, Xiangqiang Pan,* Jian Zhu, Zhengbiao Zhang*, Wei Zhang and Xiulin Zhu. Facile synthesis of well-defined redox responsive diselenide-labeled polymers via organoseleniummediated CRP and aminolysis. Polym. Chem., 2015, 6, 1367-1372.

11. Caiwei Fan, Chunlai Ding, Xiangqiang Pan, Zhengbiao Zhang*, Jian Zhu*, and Xiulin Zhu. A Straightforward Method For Preparing Well-Defined Responsive Diselenide-containing Polymers Based on ATRP. Macromolecular Rapid Communications. 2015, 36, 903-908.

12. Junfei Zhao, Yanyan Zhou, Yiwen Li, Xiangqiang Pan, Wei Zhang, Nianchen Zhou, Ke Zhang, Zhengbiao Zhang* and Xiulin Zhu*, Modular Construction of Macrocycle-based Topological Polymers via High-Efficient Thiol Chemistry, Polym. Chem., 2015, 6, 2879–2891.

13. Huaqiao Wu, Yingbo Wan, Wenxiang Wang, Yong Wang, Nianchen Zhou, Wei Zhang, Xiaohong Li,* Zhengbiao Zhang,* Xiulin Zhu, Hydrogen Bonding Promoting Controlled Radical Polymerization of 2-Vinyl Pyridine: Supramonomer for A Better Control, Polymer Chemistry, 2015, 6, 2620-2625.

14. Feng Gao, Xiangqiang Pan, Jian Zhu, Zhengbiao Zhang, Wei Zhang, Xiulin Zhu Diselenocarbamates, Novel Initiators in ATRP of Styrene, J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 1927-1933.

15. Yuwei Gu, Junfei Zhao, Qingqing Liu, Xiangqiang Pan, Wei Zhang, Zhengbiao Zhang*, Xiulin Zhu*, Zero valent metal/RAFT agent mediated CRP of functional monomers at room temperature: a promising catalyst system for CRP. Polym. Chem., 2015, 6, 359-363.

16. Yiwen Li, Hao Su, Xueyan Feng, Kan Yue, Zhao Wang, Zhiwei Lin, Xiulin Zhu, Qiang Fu, Zhengbiao Zhang*, Stephen Z. D. Cheng*, Wen-Bin Zhang*. Precision synthesis of macrocyclic giant surfactants tethered with two different polyhedral oligomeric silsesquioxanes at distinct ring locations via four consecutive "click" reactions. Polym. Chem., 2015, 6, 827-837.

17. Zhiwei Lin, Pengtao Lu, Xinfei Yu, Wen-Bin Zhang, Mingjun Huang, Kan Wu, Kai Guo, Chrys Wesdemiotis, Xiulin Zhu, Zhengbiao Zhang*, Kan Yue* and Stephen Z. D. Cheng*. Sequential “Click” Synthesis of “Nano-Diamond-Ring-like” Giant Surfactants Based on Functionalized Hydrophilic POSS/C60 Tethered with Cyclic Polystyrenes. Macromolecules 2014, 47, 4160-4168.

18. Yang Wu, Yanyan Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang*, Xiulin Zhu*. Fast conversion of terminal thiocarbonylthio group of RAFT polymer to "clickable" thiol group via the versatile sodium azide. Polym. Chem., 2014, 5, 5546-5550.

19. Wenxiang Wang, Junfei Zhao, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu* Reversible Deactivation Radical Polymerization in the Presence of Zero-Valent Metals: from Components to Precise Polymerization. Polym. Chem. 2014, 5, 3533-3546. Review Article.

20. Yang Wu, Junfei Zhao, Xiaofei Zhang, Jian Zhu, Wei Zhang, Zhengbiao Zhang* and Xiulin Zhu* Zero-valent metal catalyzed removal of thiocarbonylthio end groups from RAFT-made polystyrene: producing controllable bimodal molecular weight distribution. Polym. Chem. 2014, 5, 1992-1998.

21. Zhigui Zheng, Wenxiang Wang, Yuan Zhou, Zhengbiao Zhang* and Xiulin Zhu*. Manganese(III) acetylacetonate initiated RAFT olymerizations: an alternative and versatile RAFT nitiator. Polym. Chem. 2014, 5, 37-42.

22. Ye Cai, Jinjie Lu, Feng Zhou, Xiaoji Zhou, Nianchen Zhou*, Zhengbiao Zhang*, Xiulin Zhu* Cyclic Amphiphilic Random Copolymers Bearing Azobenzene Side Chains: Facile Synthesis and Topological Effects on Self-Assembly and Photoisomerization. Macromol. Rapid Commun. 2014, 35, 901−907.

23. Yuwei Gu, Junfei Zhao, Qingqing Liu, Nianchen Zhou, Zhengbiao Zhang*, Xiulin Zhu*. Zero-valent iron (Fe(0)) mediated RAFT miniemulsion polymerization: a facile approach for the fabrication of Fe(0)-encapsulated polymeric nanoparticles Polym. Chem., 2014, 5, 4215−4218.

24. Zhigui Zheng, Wenxiang Wang, Yuan Zhou, Zhengbiao Zhang*, Xiulin Zhu* Manganese(III) Acetylacetonate Initiated RAFT Polymerizations: An Alternative and Versatile RAFT Initiator. Polym. Chem., 2013, 10.1039/C3PY00879G.

25. Xiaofei Zhang, Wenxiang Wang, Kai Guo, Chrys Wesdemiotis, Zhengbiao Zhang*,Xiulin Zhu*. Zero-valent metal catalyzed radical-induced adjustable removal/modification of thiocarbonylthio end groups of RAFT polymer at ambient temperature. Polym. Chem., 2013, 4, 637–644.

26. Xing Zhu, Nianchen Zhou*, Jian Zhu, Zhengbiao Zhang*, Xiulin Zhu*, Wei Zhang, Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*. High-Efficiency Preparation of Macrocyclic Polymers via a Circulatory Extraction–Cyclization Strategy.Macromolecular Chemistry and Physics 2013, 214, 1107–1113.

27. Xiaoji Zhou, Wenxiang Wang, Huali Yu, Junfei Zhao, Zhengbiao Zhang*, Xiulin Zhu* Hydrogen bonding assisted reversible-deactivation radical copolymerization of 4-vinylpyridine and styrene: a facile approach for adjusting polymerization behavior, polymer composition, etc.Polym. Chem., 2013, 4, 3575–3581.

28. Wenxiang Wang, Junfei Zhao, Huali Yu, Nianchen Zhou, Zhengbiao Zhang*, Xiulin Zhu* Simultaneously improving controls over molecular weight and stereoregularity of Poly(4-vinylpyridine) via a hydrogen bonding-facilitated controlled radical polymerization.      Polymer  2013, 54, 3248–3253.

29. Wenxiang Wang, Junfei Zhao, Wei Zhang, Jian Zhu, Zhengbiao Zhang*, Xiulin Zhu* Ligand-Free SET-DTLRP of MMA at Room Temperature.     J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 1872–1879.

30. Xiao-fei Zhang, Yang Wu, Jun Huang, Xue-lang Miao, Zhengbiao Zhang*, Xiulin Zhu*. Copper(0)-mediated radical polymerization of styrene at room Temperature.Chinese Journal of Polymer Science 2013, 31, 702–712.

31. Xing Zhu, Nianchen Zhou*, Jian Zhu, Zhengbiao Zhang*, Wei Zhang, Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*. A High-Efficiency Strategy for Synthesizing Cyclic Polymers of Methacryates in One Pot. Macromol. Rapid Commun. 2013, 34, 1014−1019.

32. Yiyu Zhan, Zhengbiao Zhang*, Xiangqiang Pan, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. A Cyclic Diselenocarbamate as RAFT Agent in the Polymerization of VAc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 1475–1683

33. Junfei Zhao, Wenxiang Wang, Liangjiu Bai, Lili Zhou, Zhenping Cheng, Zhengbiao Zhang* and Xiulin Zhu*. Reversible-deactivation radical polymerization mediated by CuSO4·5H2O: an alternative and promising copper(II)-based catalyst. Polym. Chem., 2012, 3, 3220–3223.

34. Wenxiang Wang, Zhengbiao Zhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou and Xiulin Zhu* Favorable hydrogen bonding in room-temperature Cu(0)-mediated controlled radical polymerization of 4-vinylpyridine. Polym. Chem., 2012, 3, 2731–2734.

35. Lili Zhou, Zhengbiao Zhang*, Wenxiang Wang, Zhenping Cheng, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiulin Zhu Zero-Valent Bimetallic Iron/Copper Catalyzed SET-LRP: A Dual Activation by Zero-Valent Iron. J. Polym. Sci., Part A: Polym. Chem. 2012,50, 936–943.

36. Wenxiang Wang, Zhengbiao Zhang*, Yang Wu, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu. Ligand-Free Cu(0)-Mediated Controlled Radical Polymerization of Methyl Methacrylate at Ambient Temperature J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 711–719.

37. Qin Zhang, Zhengbiao Zhang*, Wenxiang Wang, Jian Zhu, Zhenping Cheng,Nianchen Zhou, Wei Zhang, Xiulin Zhu. SET-RAFT of MMA Mediated by Ascorbic Acid-Activated Copper Oxide, J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 1424–1433.

38. Huali Yu, Yang Wu, Jinlong Gao,Wenxiang Wang, Zhengbiao Zhang*, Xiulin Zhu*. Copper(0)-mediated radical copolymerization of vinyl acetate and acrylonitrile in DMSO at ambient temperature. J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 4983–4989.

39. Huali Yu, Zhengbiao Zhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. ATRP of styrene catalyzed by elemental Fe(0) and Br2: An easy and economical ATRP process. J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 2182–2187.

40. Huali Yu, Qifeng Chen, Zhengbiao Zhang*, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu*, 60Co γ-irradiation-initiated RAFT polymerization of VAc at room temperature, Reactive & Functional Polymers 2012, 72, 153–159.

41. Lili Zhou, Zhengbiao Zhang*, Zhenping Cheng, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiulin Zhu* Fe(0) Powder/CuBr2-Mediated “Living”/Controlled Radical Polymerization of Methyl Methacrylate and Styrene at Ambient TemperatureMacromol. Chem. Phys.2012, 213, 439−446.

42. Qin Zhang, Zhengbiao Zhang*, Wenxiang Wang, Zhenping Cheng, Jian Zhu, Nianchen Zhou,Wei Zhang, Zhaoqiang Wu, Xiulin Zhu*. In Situ Cu(0) Catalyzed SET–LRP: the First Attempt. J. Polym. Sci., Part A: Polym. Chem. 2011, 49, 4694–4700.

43. Zhengbiao Zhang, Wenxiang Wang, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Yonggang Yang, Yingfeng Tu, and Xiulin Zhu*. Zero–valent Iron/RAFT Agent–Mediated Polymerization of Methyl Methacrylate at Ambient Temperature.Macromolecules 2010, 43, 7979–7984.

44. Zhengbiao Zhang, ShaoJun Yuan, Xiulin Zhu, KG Neoh, ET Kang; Enzyme-mediated amperometric biosensors prepared via successive surface-initiated atom-transfer radical polymerization; Biosensors and Bioelectronics; 2010, 25, 1102–1108.

45. Zhengbiao Zhang, Wenxiang Wang, Hongda Xia, Jian Zhu, Wei Zhang and Xiulin Zhu*. Single–Electron Transfer Living Radical Polymerization (SET–LRP) of Methyl Methacrylate (MMA) with a Typical RAFT Agent as an Initiator.Macromolecules 2009, 42, 7360–7366.

46. Zhengbiao Zhang, Xiulin Zhu, FuJian Xu, KG Neoh, ET Kang. Temperature- and pH-sensitive nylon membranes prepared via consecutive surface-initiated atom transfer radical graft polymerizations; Journal of Membrane Science 2009, 342, 300–306.